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OLEIC See also:ACID, C13H34O2 or C8H07•CH: CH. [See also:CH2]7 • See also:CO2 H, an organic acid occurring as a glyceride, triolein, in nearly all fats, and in many See also:oils--See also:olive, See also:almond, See also:cod-See also:liver, &c. (see OILS). It appears as a by-product in the manufacture of candles. To prepare it olive oil is saponified with potash, and See also:lead acetate added; the lead salts are separated, dried, and extracted with See also:ether, which dissolves the lead oleate; the See also:solution is then treated with hydrochloric acid, the lead chloride filtered off, the liquid concentrated, and finally distilled under diminished pressure. Oleic acid is a colourless, odourless solid, melting at 14° and boiling at 223° (10 mm.). On exposure it turns yellow, becoming rancid. Nitric acid oxidizes it to all the fatty acids from acetic to capric. Nitrous acid gives the isomeric elaidic acid, See also:C8H,7•CH:CH•(CH2]7 •See also:CO2H, which is crystalline and melts at 51°. Hydriodic acid reduces both oleic and elaidic acids to stearic acid. Erucic acid, C8HwCH:CH•[CH2]n•CO2H, and the isomeric brassidic acid, belong to the oleic acid See also:series. They occur as glycerides in See also:rape-See also:seed oil, in the fatty oil of See also:mustard, and in the oil of See also:grape seeds. Linoleic acid, C18H32O2, found as glyceride in drying oils, and ricinoleic acid, C18H33(OH)O2, found as glyceride in See also:castor oil, closely resemble oleic acid. Additional information and CommentsThere are no comments yet for this article.
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