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NON Furoxane. such as furfuracrolein, C4H3O•CH:CH•CHO, and furfuracetone, C4H3O•CH:CH•CO•See also:CH3. With alcoholic See also:potassium See also:cyanide it changes to furoin, C4H3O.CHOH•CO•C4H3O, which can be oxidized to furil, C4H3O•CO•CO•C4H30, whilst alcoholic potash converts it into furfuryl See also:alcohol. With fatty acids and See also:acid anhydrides it gives the " See also:Perkin " reaction (see CINNAMIC ACID). Furfurol is shown to have its aldehydic See also:group in the a position, by See also:conversion into furfurpropionic acid, C4H3O•See also:CH2•CH2•See also:CO2H, which on oxidation by See also:bromine See also:water and subsequent reduction of the oxidized product is converted into n-pimelic acid, HO2C(CH2)5CO2H. Furfurol in See also:minute quantities can be detected by the red See also:colour it forms with a See also:solution of See also:aniline acetate. See also:Furfurane- aa'- dicarboxylic acid or dehydromucic acid, C4H20(CO2H)2, is formed when mucic acid is heated with hydrochloric acid at too° C. On being heated, it loses See also:carbon dioxide and gives pyromucic acid. By digesting acetoacetic ester with See also:sodium succinate and acetic anhydride, methronic acid, C8H805, is obtained; for the constitution of this acid, see L. Knorr, Ber., 1889, 22, p. 152, and R. See also:Fittig, See also:Ann., 1889, 250, p. 166. Di- and tetrahydrofurfurane compounds are also known (see A. Lipp, Ber., 1889, 22, p. 1196; W. H. Perkin, junr. Journ. Chem. See also:Soc., 1890, 57, p. 944; and S. Ruhemann, ibid., 1896, 69, p. 1383). Additional information and CommentsThere are no comments yet for this article.
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