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Athenian (n.)

1520s, "native or inhabitant of Athens;" see Athens + -ian. From 1580s as an adjective, "pertaining to Athens." Old English had Atheniense (plural noun), from Latin Atheniensis.

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Definitions of Athenian from WordNet
1
Athenian (n.)
a resident of Athens;
2
Athenian (adj.)
of or relating to or characteristic of Athens or its inhabitants;
From wordnet.princeton.edu