"part of the day from noon to evening," c. 1300, from after + noon. In 15c.-16c., the form was at afternoon; from c. 1600 it has been in the afternoon.As an adjective from 1570s. Middle English also had aftermete "afternoon, part of the day following the noon meal" (mid-14c.).
he spent a quiet afternoon in the park
after-dinner
afterglow
afterlife
aftermarket
aftermath
afternoon
aftershock
afterthought
afterward
afterwards
afterword