"pre-eminently, above all, in the first place," mid-14c., from chief (adj.) + -ly (2). Adjectival meaning "pertaining to a chief" is from 1870 (from chief + -ly (1)).
Chicom
chicory
chide
chief
chiefdom
chiefly
chieftain
chifferobe
chiffon
chiffonade
chiffonier