1560s, "causing a sensation of cold," from chill (n.) + -y (2). Meaning "feeling coldish" is attested from 1610s; figurative sense of "distant, formal, not hearty or affectionate" is by 1841. Related: Chilliness. Earlier as an adjective was simply chill "tending to cause shivering" (1510s).
a chilly greeting
Chile
chili
chiliad
chiliasm
chill
chilly
chime
chimenea
chimera
chimerical
chimichanga