"act or principle of removing local or special functions of government from immediate control of central authority," 1839, from de- + centralization. Decentralisation is attested by 1835 in German, in reference to France, but the word does not seem to appear in French before the earliest English dates.
decemvir
decency
decennial
decennoval
decent
decentralization
decentralize
deception
deceptive
decertify
decession