"put or take off" an article of clothing, especially a hat or cap, late 14c., doffen, a contraction of do off, preserving the original sense of do as "put." At the time of Johnson's Dictionary [1755] the word was "obsolete, and rarely used except by rustics," and also in literature as a conscious archaism, but it was saved from extinction (along with don (v.)) by Sir Walter Scott. However, dout and dup did not survive. Related: Doffed; doffing.