c. 1600, from event + -ful. According to OED, it is in Shakespeare, once ("As You Like It"), and there is no record of it between then and Johnson's "Dictionary." Related: Eventfully; eventfulness. Eventless is attested from 1815.
the most exhausting and eventful day of my life
an eventful decision
evening
evenly
evenness
evensong
event
eventful
eventide
eventual
eventuality
eventually
eventuate