1734, formed in American English from Latin gubernator "a governor" (see govern) + -al (1). OED marks it "Chiefly U.S.," and Century Dictionary says "Chiefly in newspaper use." As English words, gubernator was in use from 1520s, gubernation from mid-15c., but both are rare.
gubernatorial election
guardian
guardianship
Guatemala
guava
gubbertushed
gubernatorial
gudgeon
Guelph
guerdon
guerilla
Guernsey