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obdurate (adj.)

mid-15c., "stubborn, inexorable, unyielding; hardened," especially against moral influences; "stubbornly wicked," from Latin obduratus "hardened," past participle of obdurare "harden, render hard; be hard or hardened; hold out, persist, endure," in Church Latin "to harden the heart against God," from ob "against" (see ob-) + durare "harden, render hard," from durus "hard," from PIE *dru-ro-, suffixed variant form of root *deru- "be firm, solid, steadfast." Variant opturate is from early 15c. in medicine in a literal sense of "stopped, obstructed."  Related: Obdurately; obdurateness.

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Definitions of obdurate from WordNet

obdurate (adj.)
stubbornly persistent in wrongdoing;
Synonyms: cussed / obstinate / unrepentant
obdurate (adj.)
showing unfeeling resistance to tender feelings;
the child's misery would move even the most obdurate heart
Synonyms: flinty / flint / granitic / stony
From wordnet.princeton.edu