hydrocarbon of the methane series, 1872, coined from oct- "eight" (see octa-) + -ane; so called because it has eight carbon atoms. A fuel's octane rating, in reference to its anti-knocking quality, is attested from 1932.
octa-
octad
octagon
octagonal
octahedron
octane
octant
octave
Octavia
Octavian
octavo