c. 1400, "plant reputed to contain antivenom," from Old French serpentin name of a precious stone, noun use of adjective meaning "of a snake, snake-like; sly, deceptive," from Late Latin serpentius "of a serpent," from Latin serpentem (nominative serpens) "snake" (see serpent). As the name of a greenish igneous rock consisting mainly of hydrous magnesium silicate, attested from early 15c.