c. 1300, "with armor removed," from un- (1) "not" + armed, or else past-participle adjective from unarm "strip of armor" (c. 1300), from un- (2) "opposite of" + arm (v.). Meaning "not fitted to attack, weaponless" is from late 14c.
went alone and unarmed
unarmed peasants were shot down
unarmed vehicles
unappreciated
unappreciative
unapprehended
unapproachable
unapproved
unarmed
unary
unashamed
unasked
unaspiring
unassailable