1580s, "not made palatable by seasoning," from un- (1) "not" + past participle of season (v.). Meaning "not habituated by experience" is recorded from c. 1600.
unseasoned timber
unseasoned artillery volunteers
unscriptural
unscrupulous
unseal
unsearchable
unseasonable
unseasoned
unseat
unsecure
unsecured
unseeded
unseemly