1590s, "to thaw," from un- (2) "opposite of" + thaw (v.). Related: Unthawed; unthawing. Unthawed also sometimes is used with a sense "frozen" (1610s.).
untempered
untenable
untenanted
untether
untethered
unthaw
unthinkable
unthinking
unthrifty
untidy
untie