"one who liberates from bondage or restraint," 1782, agent noun in Latin form from emancipate. Emancipationist "one who favors emancipation" in any sense is from 1810 (originally in reference to religion in Ireland).
emanate
emanation
emancipate
emancipated
emancipation
emancipator
emancipatory
emarginate
emasculate
emasculation
embalm