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instance (n.)

late 14c., "urgency, insistence" (a sense now archaic), from Old French instance "effort, application; urgency, eagerness, anxiety" (13c.), from Latin instantia "presence, effort, intention; earnestness, urgency," literally "a standing near," from instans (see instant).

In logic, "a fact, a case, an example" (a sense in English from early 15c.), from Medieval Latin instantia, which translated Greek enstasis. This led to for instance "as an example" (1650s), and the noun phrase give (someone) a for instance (1953, American English). The general sense "anything that illustrates a general type" was in use by 19c.

instance (v.)

"cite as an instance" (in the logical sense), c. 1600, from instance (n.). Middle English had a verb instauncen "to plead with, urge, entreat." Related: Instanced; instancing.

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Definitions of instance from WordNet
1
instance (n.)
an occurrence of something;
another instance occurred yesterday
Synonyms: case / example
instance (n.)
an item of information that is typical of a class or group;
2
instance (v.)
clarify by giving an example of;
Synonyms: exemplify / illustrate
From wordnet.princeton.edu