1936, derogatory slang form of pink (adj.) in the political sense, used of people whose social or political views "have a tendency toward 'red;' " a metaphor that had existed at least since 1837. As an adjective by 1957.
pink-collar
Pinkerton
pink-eye
pinkie
pinkish
pinko
pinky
pinnace
pinnacle
pinnate
pinniped