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smirk (v.)

Old English smearcian "to smile." No exact cognates in other languages, but probably related to smerian "to laugh at, scorn," from Proto-Germanic *smer-, *smar-, variant of PIE *smei- "to smile;" see smile (v.), which after c. 1500 gradually restricted smirk to the unpleasant sense "smile affectedly; grin in a malicious or smug way." In some 18c. glossaries smirk is still simply "to smile." Related: Smirked; smirking. The noun is recorded by 1560s.

smirk (n.)

1550s, from smirk (v.).

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Definitions of smirk from WordNet
1
smirk (v.)
smile affectedly or derisively;
Synonyms: simper
2
smirk (n.)
a smile expressing smugness or scorn instead of pleasure;
From wordnet.princeton.edu