1775, "not having been sweetened," from un- (1) "not" + past participle of sweeten (v.); or else, if the sense is "with sweetness removed," from unsweeten (v.), which is attested from 1610s.
unsurpassed
unsuspected
unsuspecting
unsustainable
unswayed
unsweetened
unswerving
unsympathetic
unsystematic
untainted
untamed