1580s, in the moral sense; c. 1600 in the physical sense; from un- (1) "not" + past participle of taint (v.). Earlier was untained (mid-15c.), from a Middle English variant of taint (v.).
unswayed
unsweetened
unswerving
unsympathetic
unsystematic
untainted
untamed
untangible
untangle
untapped
untaught