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untried (adj.)

1510s, "not proven or tested," from un- (1) "not" + tried.

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Definitions of untried from WordNet

untried (adj.)
not tried or tested by experience;
an illustrator untried in mural painting
Synonyms: unseasoned / untested / young
untried (adj.)
not yet proved or subjected to testing;
an untried procedure
Synonyms: untested
From wordnet.princeton.edu