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PYRENE, C16H

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Originally appearing in Volume V22, Page 687 of the 1911 Encyclopedia Britannica.
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PYRENE, C16H ,o, a See also:hydrocarbon found together with chrysene in the last portion of the See also:coal See also:tar distillate, and also in " Stupp " See also:fat. The crude solid product from the tar distillate is digested with See also:carbon bisulphide to dissolve the pyrene, the See also:solution filtered and the solvent evaporated. The See also:residue is dissolved in See also:alcohol and to the See also:cold saturated solution a cold alcoholic solution of picric See also:acid is added. The picrate so formed is then decomposed by See also:ammonia. On its separation from " Stupp " fat see E. See also:Bamberger and M. See also:Philip, See also:Ann., 1887, 240, p. 161. It crystallizes in See also:monoclinic tables which melt at 148-149° C. Chromic acid oxidizes it to pyrene quinone, C,6H,02, and pyrenic acid, C16H,606. The picrate, which is easil1 soluble in See also:benzene, crystallizes in See also:long red needles melting at 222 . When heated with hydriodic acid and See also:phosphorus to zoo° C. it yields a hexahydride.

It has been obtained synthetically by M. See also:

Freund and H. Michaels (Ber., 1897, 30, p. 1383) by distilling thebenol over See also:zinc dust in a stream of See also:hydrogen, or by the See also:action of hydriodic acid and phosphorus at 220° C. on thebenol.

End of Article: PYRENE, C16H

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