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ILMENITE , a See also:mineral known also as titanic See also:iron, formerly regarded as an iron and See also:titanium sesquioxide (Fe,Ti)203 isomoX-phous with See also:haematite (Fe203), but now generally considered to be an iron titanate FeTiO3 isomorphous with pyrophanite (MnTiOa) and geikielite (MgTiO3). It crystallizes in the.parallell-
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faced helnihedral class of the See also:rhombohedral See also:system, thus having the same degree of symmetry as See also:phenacite and pyrophanite, but differing from that of haematite. The angles between the faces are very nearly the same as between the corresponding faces of haematite; but it is to be noted that the rhombohedral See also:angle (94° 29') of ilmenite is not intermediate between that of haematite (94° o') and of the artificially prepared crystals of titanium sesquioxide (92° 40'), which should be the See also:case if the three substances were isomorphous. Analyses show wide See also:variations in chemical See also:composition, and there is a gradation from normal ilmenite FeTiO3 (with titanium dioxide 52.7, and ferrous See also:oxide 47.3%) to titaniferous haematite and titaniferous See also:magnetite. Frequently also,
See also:magnesia and manganous oxide are See also:present in small amounts, the former reaching 16%. The See also:formula (Fe,Mg)TiO3 is then analogous to those of geikielite and pyrophanite. Many analyses show the presence of TiO2 and (Fe,Mg)O in this ratio of 1:1, yet there is often an excess of ferric oxide to be accounted for; this may perhaps be explained by the See also:regular intergrowth on a See also:minute See also:scale of. ilmenite with haematite, like the intergrowth of such substances as See also:calcite and See also:sodium nitrate, which are similar crystallographically but not chemically.
In many of its See also:external characters ilmenite is very similar to haematite; the crystals often have the same See also:tabular or lamellar See also:habit; the twin-See also:laws are the same, giving rise to twin-lamellae and planes of parting parallel to the basal See also:plane and the See also:primitive rhombohedron; the See also:colour is iron-See also:black with a submetallic lustre; finally, the conchoidal fracture is the same in both minerals. Ilmenite has a black streak; it is opaque, but in very thin scales .sometimes transparent with a clove-See also: Crichtonite occurs as small and brilliant crystals of acute rhombohedral habit on See also:quartz at Le Bourg d'Oisans in See also:Dauphine; it agrees closely in composition with the formula FeTiO3 and has a specific gravity of 4.7. Manaccanite (or Menaccanite) is a black sandy material, first found in 1791 in a stream at Manaccan near See also:Helston in See also:Cornwall. Iserite, from Iserwiese in the Iser Mountains, Bohemia, is a similar See also:sand, but containing some octahedral crystals, possibly of titaniferous magnetite. Washingtonite is found as large tabular crystals at See also:Washington, See also:Connecticut. Uddevallite is from Uddevalla in See also:Sweden. Picrotitanite or picroilmenite (Gr. snobs, " See also:bitter ") is the name given to varieties containing a considerable amount of magnesia. Other varieties are kibdelophane, hystatite, &c. The name ilmenite, proposed by A. T. Kupffer in 1827, is after the Ilmen Mountains in the See also:southern Urals, whence come the best crystals of the mineral. The largest crystals, sometimes as much as 16 lb in See also:weight, are from Kragero and See also:Arendal in See also:Norway. Ilmenite occurs, often in association with magnetite, in gneisses and See also:schists, sometimes forming beds of considerable extent, but of little or no economic value. It is a See also:common See also:accessory constituent of igneous rocks of all kinds, more especially basic rocks such as See also:gabbro, See also:diabase and See also:basalt. Iu these rocks it occurs as platy crystals, and is frequently re--presented by a See also: Additional information and CommentsThere are no comments yet for this article.
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