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ILMENITE

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Originally appearing in Volume V14, Page 327 of the 1911 Encyclopedia Britannica.
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ILMENITE , a See also:

mineral known also as titanic See also:iron, formerly regarded as an iron and See also:titanium sesquioxide (Fe,Ti)203 isomoX-phous with See also:haematite (Fe203), but now generally considered to be an iron titanate FeTiO3 isomorphous with pyrophanite (MnTiOa) and geikielite (MgTiO3). It crystallizes in the.parallell- ILOILO 327 faced helnihedral class of the See also:rhombohedral See also:system, thus having the same degree of symmetry as See also:phenacite and pyrophanite, but differing from that of haematite. The angles between the faces are very nearly the same as between the corresponding faces of haematite; but it is to be noted that the rhombohedral See also:angle (94° 29') of ilmenite is not intermediate between that of haematite (94° o') and of the artificially prepared crystals of titanium sesquioxide (92° 40'), which should be the See also:case if the three substances were isomorphous. Analyses show wide See also:variations in chemical See also:composition, and there is a gradation from normal ilmenite FeTiO3 (with titanium dioxide 52.7, and ferrous See also:oxide 47.3%) to titaniferous haematite and titaniferous See also:magnetite. Frequently also, See also:magnesia and manganous oxide are See also:present in small amounts, the former reaching 16%. The See also:formula (Fe,Mg)TiO3 is then analogous to those of geikielite and pyrophanite. Many analyses show the presence of TiO2 and (Fe,Mg)O in this ratio of 1:1, yet there is often an excess of ferric oxide to be accounted for; this may perhaps be explained by the See also:regular intergrowth on a See also:minute See also:scale of. ilmenite with haematite, like the intergrowth of such substances as See also:calcite and See also:sodium nitrate, which are similar crystallographically but not chemically. In many of its See also:external characters ilmenite is very similar to haematite; the crystals often have the same See also:tabular or lamellar See also:habit; the twin-See also:laws are the same, giving rise to twin-lamellae and planes of parting parallel to the basal See also:plane and the See also:primitive rhombohedron; the See also:colour is iron-See also:black with a submetallic lustre; finally, the conchoidal fracture is the same in both minerals. Ilmenite has a black streak; it is opaque, but in very thin scales .sometimes transparent with a clove-See also:brown colour. It is slightly magnetic, but without See also:polarity. The hardness is 51, and the specific gravity varies with the chemical composition from 4.3 to 5.o. Owing to the wide variations in composition, which even yet are not properly understood, several varieties of the mineral have been distinguished by See also:special names.

Crichtonite occurs as small and brilliant crystals of acute rhombohedral habit on See also:

quartz at Le Bourg d'Oisans in See also:Dauphine; it agrees closely in composition with the formula FeTiO3 and has a specific gravity of 4.7. Manaccanite (or Menaccanite) is a black sandy material, first found in 1791 in a stream at Manaccan near See also:Helston in See also:Cornwall. Iserite, from Iserwiese in the Iser Mountains, Bohemia, is a similar See also:sand, but containing some octahedral crystals, possibly of titaniferous magnetite. Washingtonite is found as large tabular crystals at See also:Washington, See also:Connecticut. Uddevallite is from Uddevalla in See also:Sweden. Picrotitanite or picroilmenite (Gr. snobs, " See also:bitter ") is the name given to varieties containing a considerable amount of magnesia. Other varieties are kibdelophane, hystatite, &c. The name ilmenite, proposed by A. T. Kupffer in 1827, is after the Ilmen Mountains in the See also:southern Urals, whence come the best crystals of the mineral. The largest crystals, sometimes as much as 16 lb in See also:weight, are from Kragero and See also:Arendal in See also:Norway. Ilmenite occurs, often in association with magnetite, in gneisses and See also:schists, sometimes forming beds of considerable extent, but of little or no economic value.

It is a See also:

common See also:accessory constituent of igneous rocks of all kinds, more especially basic rocks such as See also:gabbro, See also:diabase and See also:basalt. Iu these rocks it occurs as platy crystals, and is frequently re--presented by a See also:white, opaque alteration product known as leucoxene. (L. J.

End of Article: ILMENITE

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