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See also:BLACK, See also:JEREMIAH See also:SULLIVAN (1810–1883) , See also:American lawyer and statesman, was See also:born in Stony See also:Creek township, See also:Somerset See also:county, See also:Pennsylvania, on the loth of See also:January 181o. He was largely self-educated, and before he was of See also:age was admitted to the Pennsylvania See also:bar. He gradually became one of the leading American lawyers, and in 1851–1857 was a member of the supreme See also:court of Pennsylvania (See also:chief-See also:justice 1851-1854). In 18s7 he entered See also:President See also:Buchanan's See also:cabinet as See also:attorney See also:general of the See also:United States. In this capacity he successfully contested the validity of the " See also:California See also:land claims "—claims to about 19,000 sq. m. of land, fraudulently alleged to have been granted to land-grabbers and others by the Mexican See also:government See also:prior to the See also:close of the Mexican See also:War. From the 17th of See also:December 186o to the 4th of See also: Black was also for a See also:short See also:time counsel for President See also:Andrew Johnson, in his trial on the See also:article of See also:impeachment, before the United States See also:Senate, and for See also: The causticity of alkaline bodies was explained at that time as depending on the presence in them of the principle of See also:fire, " phlogiston "; quicklime, for instance, was See also:chalk which had taken up phlogiston, and when mild alkalis such as See also:sodium or See also:potassium carbonate were causticized by its aid, the phlogiston was supposed to pass from it to them. Black showed that on the contrary causticization meant the loss of something, as proved by loss of See also:weight; and this something he found to be an " See also:air," which, because it was fixed in the substance before it was causticized, he spoke of as " fixed air." Taking See also:magnesia See also:alba, which he distinguished from See also:limestone with which it had previously been confused, he showed that on being heated it lost weight owing to the See also:escape of this fixed air (named carbonic See also:acid by See also:Lavoisier in 1781), and that the weight was regained when the calcined product was made to reabsorb the fixed air with which it had parted. These investigations, by which Black not only gave a See also:great impetus to the chemistry of gases by clearly indicating the existence of a See also:gas distinct from See also:common air, but also anticipated Lavoisier and See also:modern chemistry by his See also:appeal to the See also:balance, were described in the thesis De humore acido a cibis orto, et magnesia alba, which he presented for his See also:doctor's degree in 1754; and a See also:fuller See also:account of them was read before the Medical Society of See also:Edinburgh in See also:June 1755, and published in the following See also:year as Experiments upon magnesia, quicklime and some other alkaline substances. It is curious that Black See also:left to others the detailed study of this " fixed air " he had discovered. Probably the explanation is pressure of other See also:work. In 1756 he succeeded Cullen as lecturer in chemistry at Glasgow, and was also appointed professor of See also:anatomy, though that See also:post he was glad to See also:exchange for the See also:chair of medicine. The preparation of lectures thus took up much of his time, and he was also gaining an extensive practice as a physician. Moreover, his See also:attention was engaged on studies which ultimately led to his See also:doctrine of latent See also:heat. He noticed that when See also:ice melts it takes up a quantity of heat without undergoing any See also:change of temperature, and he argued that this heat, which as was usual in his time- he looked upon as a subtle fluid, must have combined with the particles of ice and thus become latent government might be exercised without infringing on the rights_ in its substance. This See also:hypothesis he verified quantitatively by experiments, performed at the end of 1761. In 1764, with the aid of his assistant, William See also:Irvine (1743-1787), he further measured the latent heat of See also:steam, though not very accurately. This doctrine of latent heat he taught in his lectures from 1761 onwards, and in See also:April 1762 he described his work to a See also:literary society in Glasgow. But he never published any detailed account of it, so that others, such as J. A. See also:Deluc, were able to claim the See also:credit of his results. In the course.of his inquiries he also noticed that different bodies in equal masses require different amounts of heat to raise them to the same temperature, and so founded the doctrine of specific heats; he also showed that equal additions or abstractions of heat produced equal See also:variations of bulk in the liquid of his thermometers. In 1766 he succeeded Cullen in the chair of chemistry in Edinburgh, where he devoted practically all his time to the preparation of his lectures. Never very robust, his See also:health gradually became weaker and ultimately he was reduced to the See also:condition of a valetudinarian. In 1795 he received the aid of a coadjutor in his professorship, and two years later he lectured for the last time. He died in Edinburgh on the 6th of December 1799 (not on the 26th of See also:November as stated in Robison's See also:life). As a scientific investigator, Black was conspicuous for the carefulness of his work and his caution in See also:drawing conclusions. Holding that chemistry had not attained the See also:rank of a science—his lectures dealt with the "effects of heat and mixture"—he had an almost morbid horror of hasty generalization or of anything that had the pretensions of a fully fledged See also:system. This See also:mental attitude, combined with a certain lack of initiative and the weakness of his health, probably prevented him from doing full justice to his splendid See also:powers of experimental See also:research. Apart from the work already mentioned he published only two papers during his life-time—" The supposed effect of boiling on water, in disposing it to freeze more readily " (Phil. Trans., 1775), and " An See also:analysis of the See also:waters of the hot springs in See also:Iceland " (Trans. See also:Roy. See also:Soc. Ed., 1794).
After his See also:death his lectures were written out from his own notes, supplemented by those of some of his pupils, and published with a biographical See also:preface by his friend and colleague, Professor See also: Additional information and CommentsThere are no comments yet for this article.
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