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LAVOISIER, ANTOINE LAURENT (1743-1794)

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Originally appearing in Volume V16, Page 297 of the 1911 Encyclopedia Britannica.
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LAVOISIER, See also:ANTOINE See also:LAURENT (1743-1794) , See also:French chemist, was See also:born in See also:Paris on the 26th of See also:August 1743. His See also:father, an avocat au See also:parlement, gave him an excellent See also:education at the See also:college See also:Mazarin, and encouraged his See also:taste for natural See also:science; and he studied See also:mathematics and See also:astronomy with N. L. de See also:Lacaille, See also:chemistry with the See also:elder See also:Rouelle and See also:botany with See also:Bernard de See also:Jussieu. In 1766 he received a See also:gold See also:medal from the See also:Academy of Sciences for an See also:essay on the best means of See also:lighting a large See also:town; and among his See also:early See also:work were papers on the See also:analysis of See also:gypsum, on See also:thunder, on the See also:aurora and on congelation, and a refutation of the prevalent belief that See also:water by repeated See also:distillation is converted into See also:earth. He also assisted J. E. See also:Guettard (1715—1786) in preparing his mineralogical See also:atlas of See also:France. In 1768, recognized as a See also:man who had both the ability and the means for a scientific career, he was nominated adjoins chimiste to the Academy, and in that capacity made numerous reports on the most diverse subjects, from the theory of See also:colours to water-See also:supply and from invalid chairs to mesmerism and the See also:divining See also:rod. The same See also:year he obtained the position of adjoins to Baudon, one of the farmers-See also:general of the See also:revenue, subsequently becoming a full titular member of the See also:body. This was the first of a See also:series of posts in which his administrative abilities found full See also:scope. Appointed regisseur See also:des poudres in 1775, he not only abolished the vexatious See also:search for See also:saltpetre in the cellars of private houses, but increased the See also:production of the See also:salt and improved the manufacture of See also:gunpowder. In 1785 he was nominated to the See also:committee on See also:agriculture, and as its secretary See also:drew up reports and instructions on the cultivation of various crops, and promulgated schemes for the See also:establishment of experimental agricultural stations, the See also:distribution of agricultural implements and the See also:adjustment of rights of pasturage.

Seven years before he had started a See also:

model See also:farm at Frechine, where he demonstrated the advantages of scientific methods of cultivation and of the introduction of See also:good breeds of See also:cattle and See also:sheep. Chosen a member of the provincial See also:assembly of See also:Orleans in 1787, he busied himself with plans for the improvement of the social and economic conditions of the community by means of savings See also:banks, See also:insurance See also:societies, canals, workhouses, &c.; and he showed the sincerity of his philanthropical work by advancing See also:money out of- his own See also:pocket, without See also:interest, to the towns of See also:Blois and See also:Romorantin, for the See also:purchase of See also:barley during the See also:famine of 1788. Attached in this same year to the caisse d'escompte, he presented the See also:report of its operations to the See also:national assembly in 1789, and as See also:commissary of the See also:treasury in 1791 he established a See also:system of accounts of unexampled punctuality. He was also asked by the national assembly to draw up a new See also:scheme of See also:taxation in connexion with which he produced a report De la richesse territoriale de la France, and he was further associated with committees on See also:hygiene, coinage, the casting of See also:cannon, &c., and was secretary and treasurer of the See also:commission appointed in 1790 to secure uniformity of weights and See also:measures. In 1791, when Lavoisier was in the See also:middle of all this See also:official activity, the suppression of the farmers-general marked the beginning of troubles which brought about his See also:death. His membership of that body was alone sufficient to make him an See also:object of suspicion; his See also:administration at the regie des poudres was attacked; and See also:Marat accused him in the Ami du Peuple of putting Paris in See also:prison and of stopping the circulation of See also:air in the See also:city by the mur d'See also:octroi erected at his See also:suggestion in 1787. The Academy, of which as treasurer at the See also:time he was a See also:con- he assigned to dephlogisticated air the name See also:oxygen, or " See also:acid-producer," on the supposition that all acids were formed by its See also:union with a See also:simple, usually non-metallic, body; and having verified this notion for See also:phosphorus, See also:sulphur, See also:charcoal, &c., and even extended it to the See also:vegetable acids, he naturally asked himself what was formed by the See also:combustion of " inflammable air " (See also:hydrogen). This problem he had attacked in 1774, and in subsequent years he made various attempts to discover the acid which, under the See also:influence of his oxygen theory, he expected would be formed. It was not till the 25th of See also:June 1783 that in See also:conjunction with See also:Laplace he announced to the Academy that water was the product formed by the See also:combination of hydrogen and oxygen, but by that time he had been anticipated by See also:Cavendish, to whose See also:prior work, however, as to that of several other investigators in other matters, it is to be regretted that he did not render due See also:acknowledgment. But a knowledge of the See also:composition of water enabled him to See also:storm the last defences of the phlogistonists. Hydrogen they held to be the phlogiston of metals, and they supported this view by pointing out that it was liberated when metals were dissolved in acids. Considerations of See also:weight had See also:long prevented Lavoisier from accepting this See also:doctrine, but he was now able to explain the See also:process fully, showing that the hydrogen evolved did not come from the See also:metal itself, but was one product of the decomposition of the water of the dilute acid, the other product, oxygen, combining with the metal to See also:form an See also:oxide which in turn See also:united with the acid.

A little later this same knowledge led him to the beginnings of quantitative organic analysis. Knowing that the water produced by the combustion of See also:

alcohol was not pre-existent in that sub-stance but was formed by the combination of its hydrogen with the oxygen of the air, he burnt alcohol and other combustible organic substances, such as See also:wax and oil, in a known See also:volume of oxygen, and, from the weight of the water and See also:carbon dioxide produced and his knowledge of their composition, was able to calculate the amounts of carbon, hydrogen and oxygen See also:present in the substance. Up to about this time Lavoisier's work, mainly quantitative in See also:character, had appealed most strongly to physicists, but it now began to win conviction from chemists also. C. L. Berthollet, L. B. Guyton de Morveau and A. F. See also:Fourcroy, his collaborators in the reformed system of chemical terminology set forth in 1787 in the Methode de momenclature chimique, were among the earliest French converts, and they were followed by M. H. See also:Klaproth and the See also:German Academy, and by most See also:English chemists except Cavendish, who rather suspended his See also:judgment, and See also:Priestley, who stubbornly clung to the opposite view.

Indeed, though the partisans of phlogiston did not surrender without a struggle, the See also:

history of science scarcely presents a second instance of a See also:change so fundamental accomplished with such ease. The spread of Lavoisier's doctrines was greatly facilitated by the defined and logical form in which he presented them in his Traite elementaire de chimie (presente daps un ordre nouveau et d'apres See also:les decouvertes modernes) (1789). The See also:list of simple substances contained in the first volume of this work includes See also:light and caloric with oxygen, azote and hydrogen. Under the See also:head of " oxidable or acidifiable " substances, the combination of which with oxygen yielded acids, were placed sulphur, phosphorus, carbon, and the muriatic, fluoric and boracic radicles. The metals, which by combination with oxygen became oxides, were See also:antimony, See also:silver, See also:arsenic, See also:bismuth, See also:cobalt, See also:copper, See also:tin, See also:iron, See also:manganese, See also:mercury, See also:molybdenum, See also:nickel, gold, See also:platinum, See also:lead, See also:tungsten and See also:zinc; and the " simple earthy salifiable sub-stances " were See also:lime, baryta, See also:magnesia, alumina and See also:silica. The simple nature of the alkalies Lavoisier considered so doubtful that he did not class them as elements, which he conceived as substances which could not be further decomposed by any known process of analysis—les molecules simples et indivisibles qui See also:corn posent les See also:corps. The union of any two of the elements gave rise to binary compounds, such as oxides, acids, sulphides, &c. A substance containing three elements was a binary See also:compound of the second See also:order; thus salts, the most important compounds of this class, were formed by the union of acids andoxides, iron sulphate, for instance, being a compound of iron oxide with sulphuric acid. In addition to his purely chemical work, Lavoisier, mostly in conjunction with Laplace, devoted considerable See also:attention to See also:physical problems, especially those connected with See also:heat. The two carried out some of the earliest thermochemical investigations, devised apparatus for measuring linear and cubical expansions, and employed a modification of See also:Joseph See also:Black's See also:ice calorimeter in a series of determinations of specific heats. Regarding heat (matiere de See also:feu or fluide igne) as a See also:peculiar See also:kind of imponderable See also:matter, Lavoisier held that the three states of See also:aggregation—solid, liquid and See also:gas—were modes of matter, each depending on the amount of matiere de feu with which the ponderable substances concerned were interpenetrated and combined; and this view enabled him correctly to anticipate that gases would be reduced to liquids and solids by the influence of See also:cold and pressure. He also worked at See also:fermentation, respiration and See also:animal heat, looking upon the processes concerned as essentially chemical in nature.

A See also:

paper discovered many years after his death showed that he had anticipated later thinkers in explaining the cyclical process of animal and vegetable See also:life, for he pointed out that See also:plants derive their See also:food from the air, from water, and in general from the See also:mineral See also:kingdom, and animals in turn feed on plants or on other animals fed by plants, while the materials thus taken up by plants and animals are restored to the mineral kingdom by the breaking-down processes of fermentation, putrefaction and combustion. A See also:complete edition of the writings of Lavoisier, Euvres de Lavoisier, publiees See also:par les soins du ministre de l'instruction publique, was issued at Paris in six volumes from 1864-1893. This publication comprises his Opuscules physiques et chimiques (1774), many See also:memoirs from the Academy volumes, and numerous letters, notes and reports See also:relating to the various matters on which he was engaged. At the time of his death he was preparing an edition of his collected See also:works, and the portions ready for the See also:press were published in two volumes as Memoires de chimie in 18o5 by his widow (in that year married to See also:Count See also:Rumford), .who had See also:drawn and engraved the plates in his Traite elementaire de chimie (1789). See E. Grimaux, Lavoisier 1743-1794, d'apres sa correspondance, ses See also:manuscripts, &c. (1888), which gives a list of his works; P. E. M. See also:Berthelot, La Revolution chimique: Lavoisier (1890), which contains an analysis of and extracts from his laboratory notebooks. LA VOISIN. See also:CATHERINE MoNvolsIN, known as "La Voisin " (d.

168o), French sorceress, whose See also:

maiden name was Catherine See also:Deshayes, was one of the See also:chief personages in the famous affaire des poisons, which disgraced the reign of See also:Louis XIV. Her See also:husband, Monvoisin, was an unsuccessful jeweller, and she practised See also:chiromancy and See also:face-See also:reading to retrieve their fortunes. She gradually added the practice of See also:witchcraft, in which she had the help of a renegade See also:priest, See also:Etienne Guibourg, whose See also:part was the celebration of the " black See also:mass," an abominable See also:parody in which the See also:host was compounded of the See also:blood of a little See also:child mixed with horrible ingredients. She practised See also:medicine, especially midwifery, procured See also:abortion and provided love powders and poisons. Her chief See also:accomplice was one of her lovers, the magician Lesage, whose real name was See also:Adam Ceeuret. The See also:great ladies of Paris flocked to La Voisin, who accumulated enormous See also:wealth. Among her clients were Olympe See also:Mancini, comtesse de See also:Soissons, who sought the death of the See also:king's See also:mistress, See also:Louise de la Valliere; Mme de See also:Montespan, Mme de See also:Gramont (la belle See also:Hamilton) and others. The bones of toads, the See also:teeth of moles, See also:cantharides, iron filings, human blood and human dust were among the ingredients of the love powders concocted by La Voisin. Her knowledge of poisons was not apparently so thorough as that of less well-known sorcerers, or it would be difficult to See also:account for La V alliere's See also:immunity. The See also:art of poisoning had become a See also:regular science. The death of Henrietta, duchess of Orleans, was attributed, falsely it is true, to See also:poison, and the crimes of See also:Marie Madeleine de Brinvilliers (executed in 1676) and her accomplices were still fresh in the public mind. In See also:April 1679 a commission appointed to inquire into the subject and to prosecute the offenders met for the first time.

Its proceedings, including some suppressed in the official records, are preserved in the notes of one of the official rapporteurs, See also:

Gabriel See also:Nicolas de la Reynie. The See also:revelation of the treacherous intention of Mme de Montespan to poison Louis XIV. and of other crimes, planned by personages who could not be attacked without See also:scandal which touched the See also:throne, caused Louis XIV. to See also:close the chambre ardente, as the See also:court was called, on the 1st of See also:October 1680. It was reopened on the 19th of May 1681 and sat until the 21st of See also:July 1682. Many of the culprits escaped through private influence. Among these were Marie See also:Anne Mancini, duchesse de See also:Bouillon, who had sought to get rid of her husband in order to marry the See also:duke of See also:Vendome, though Louis XIV. banished her to See also:Nerac. Mme de Montespan was not openly disgraced, because the preservation of Louis's own dignity was essential, and some See also:hundred prisoners, among them the infamous Guibourg and Lesage, escaped the See also:scaffold through the suppression of See also:evidence insisted on by Louis XIV. and See also:Louvois. Some of these were imprisoned in various fortresses, with instructions from Louvois to the respective commandants to flog them if they sought to impart what they knew. Some See also:innocent persons were imprisoned for life because they had knowledge of the facts. La Voisin herself was executed at an early See also:stage of the proceedings, on the 20th of See also:February 168o, after a perfunctory application of See also:torture. The authorities had every See also:reason to avoid further revelations. See also:Thirty-five other prisoners were executed; five were sent to the galleys and twenty-three were banished. Their crimes had furnished one of the most extraordinary trials known to history.

See F. Ravaisson, Archives de la See also:

Bastille, vols. iv.-vii. (187o–1874) ; the notes of La Reynie, preserved in the Bibliotheque Nationale; F. Funck-See also:Brentano, Le Drame des poisons (1899); A. See also:Masson, La Sorcellerie et la science des poisons an X VIP siecle (1904). See also:Sardou made the affair a background for his Affaire des poisons (1907). There is a portrait of La Voisin by Antoine See also:Coypel, which has been often reproduced.

End of Article: LAVOISIER, ANTOINE LAURENT (1743-1794)

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