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PHENAZINE (Azophenylene), C12H5N2

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Originally appearing in Volume V21, Page 365 of the 1911 Encyclopedia Britannica.
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PHENAZINE (Azophenylene), C12H5N2 , in organic See also:chemistry, the See also:parent substance of many dyestuffs, e.g. the eurhodines, toluylene red, See also:indulines and safranines. It is a dibenzoparadiazine having the See also:formula given below. It may be obtained by distilling See also:barium azobenzoate (A. Claus, Ber., 1873, 6, p. 723); by passing See also:aniline vapour over See also:lead See also:oxide, or by the oxidation of dihydrophenazine, which is prepared by See also:heating See also:pyrocatechin with orthophenylene diamine (C. Ris, Ber., 1886, 19, p. 2206). It is also formed when ortho-amipodiphenylamine is distilled over lead peroxide (O. See also:Fischer and E. Hepp). It crystallizes in yellow needles which melt at 1710 C., and are only sparingly soluble in See also:alcohol. Sulphuric See also:acid dissolves it, forming a deep-red See also:solution.

The more complex phenazines, such as the naphthophenazines, naphthazines and naphthotolazines, may be prepared by condensing ortho-diamines with ortho-See also:

quinones (O. Hinsberg, See also:Ann., 1887, 237, p. 340); by the oxidation of an ortho-diamine in the presence of a-naphthol (0. Witt), and by the decomposition of ortho-anilido-(-toluidido- &c.)-See also:azo compounds with dilute acids. If alkyl or aryl-ortho-diamines be used azonium bases are obtained. The azines are mostly yellow in See also:colour, distil unchanged and are See also:stable to oxidants. They add on alkyl iodides readily, forming alkyl azonium salts. anhydride formation also taking See also:place between these hydroxyl See also:groups. It dissolves in concentrated sulphuric acid with a yellowish-See also:green See also:fluorescence. The rhodamines, which are closely related to the phthaleins, are formed by the condensation of the alkyl metaaminophenols with See also:phthalic anhydride in the presence of sulphuric acid. Their salts are See also:fine red dyes. By the entrance of amino or hydroxyl groups into the See also:molecule .

PHENOMENON (Gr. 4,atvo..cevov, a thing seen, from cbaiveuOat, dyestuffs are formed. The mono-amino derivatives or eurhodines I to appear in See also:

ordinary See also:language a thin rocess event &c., are obtained when the arvlmonamines are condensed with ortho- )' g g °' p ' ' amino zo compounds; by condensing quinone dichlorimide or I observed by the senses. Thus the rising of the See also:sun, a thunderpara-nitrosodimethyl aniline with monamines containing a See also:free I See also:storm, an See also:earthquake are natural " phenomena." From this springs the incorrect colloquial sense, something out of the See also:common, an event which especially strikes the See also:attention; hence such phrases as " phenomenal " activity. In See also:Greek See also:philosophy phenomena are the changing See also:objects of the senses as opposed to essences (ra See also:aura) which are one and permanent, and are therefore regarded as being more real, the objects of See also:reason rather than of senses which are " See also:bad witnesses." In See also:modern philosophy the phenomenon is neither the " thing-in-itself," nor the See also:noumenon (q.v.) or See also:object of pure thought, but the thing-in-itself as it appears to the mind in sensation (see especially See also:KANT; and See also:METAPHYSICS). In this sense the subjective See also:character is of See also:prime importance. Among derivative terms are " Phenomenalism" and "Phenomenology." Phenomenalism is either (I) the See also:doctrine that there can be no knowledge except by phenomena, i.e. sense-given data, or (2) the doctrine that all known things are phenomena, i.e. that there are no " things-inthemselves." " Phenomenology " is the See also:science of phenomena: every See also:special science has a special See also:section in which its particular phenomena are described. The See also:term was first used in See also:English in the 3rd edition of the Ency. Brit. in the See also:article " Philosophy " by J. Robison. Kant has a special use of the term for that See also:part of the Metaphysic of Nature which considers See also:motion and See also:rest as predicates of a See also:judgment about things.

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