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PHENACODUS , one of the earliest and most See also:primitive of the ungulate mammals, typifying the See also:family Phenacodontidae and the sub-See also:order Condylarthra. The typical Phenacodus primaevus, of the See also:Lower or Wasatch See also:Eocene of See also:North See also:America, was a relatively small ungulate, of slight build, with straight limbs each terminating in five See also:complete toes, and walking in the digitigrade See also:fashion of the See also:modern See also:tapir. The See also:middle toe was the largest, and the See also:weight of the See also:body was mainly supported on this and the two adjoining digits, which appear to have been encased in hoofs, thus foreshadowing the tridactyle type See also:common in perissodactyle and certain See also:extinct See also:groups of ungulates. The See also:skull was small, with proportionately See also:minute See also:brain; and the arched back, strong lumbar vertebrae, See also:long and powerful tail, and comparatively feeble fore-quarters all proclaim kinship with the primitive creodont See also:Carnivora (see See also:CREODONTA), from which Phenacodus and its See also:allies, and through them the more typical See also:Ungulata, are probably derived. All the bones of the limbs are See also:separate, and those of the carpus and See also:tarsus do not alternate; that is to say, each one in the upper See also:row is placed immediately above the corresponding one in the row below. The full See also:series of See also:forty-four See also:teeth was See also:developed; and the upper molars were See also:short-crowned, or brachyodont, with six See also:low cones, two See also:internal, two intermediate and two See also:external, so that they were of the typical primitive bunodont structure. In habits the See also:animal was See also:cursorial and herbivorous. or possibly carnivorous. In the Puerco, or Lowest Eocene of North America the See also:place of the above See also:species was taken by Euprotogonia puercensis, an animal only See also:half the See also:size of Phenacodus primaevus, with the terminal See also:joints of the limbs intermediate between hoofs and claws, and the first and fifth toes taking their full See also:share in the support of the weight of the body. These two genera may be regarded as forming the earliest stages in the See also:evolution of the See also:horse, coming below Hyracotherium (see See also:EQUIDAE). As ancestors of the Artiodactyle See also:section of the Ungulata, we may look to forms more or less closely related to the North See also:American Lower Eocene genera Mioclaenus and Pantolestes, respectively typifying the families Mioclaenidae and Pantolestidae. They were five-toed, bunodont Condylarthra, with a decided approximation to the perissodactyle type in the structure of the feet. A third type of Condylarthra from the North American Lower Eocene is represented by the family Meniscotheriidae, including the genera Meniscotherium and Hyracops. These, it is suggested, may have been related to the ancestral See also:Hyracoidea. Teeth and jaws probably referable to the Condylarthra have been obtained in See also:European See also:early See also:Tertiary formations. All Ungulata probably originated from Condylarthra. See H. F. See also:Osborn, See also:Skeleton of Phenacodus primaevus; comparison with Euprotogonia, See also:Bull. Amer. See also:Mus. x. 159. (R. L.*) PHENANTHRENE, C14HIo, a See also:hydrocarbon isomeric with See also:anthracene, with which it occurs in the fraction of the See also:coal See also:tar distillate boiling between 2700—400° C. It may be separated from the anthracene oil by repeated fractional See also:distillation, followed by fractional See also:crystallization from See also:alcohol (anthracene being the less soluble), and finally purified by oxidizing any residual anthracene with See also:potassium bichromate and sulphuric See also:acid (R. Anschutz and G. See also:Schultz, See also:Ann., 1879, 196, p. 35); or the two See also:hydrocarbons may be separated by See also:carbon bisulphide, in which anthracene is insoluble. It is formed when the vapours of See also:toluene, stilbene, dibenzyl, ortho-ditolyl, or coumarone and See also:benzene are passed through a red-hot See also:tube; by distilling See also:morphine with See also:zinc dust; and, with anthracene, by the See also:action of See also:sodium on ortho-brombenzyl bromide (C. L. See also:Jackson and J. F. See also: Its solutions in alcohol and See also:ether have a faint See also:blue See also:fluorescence. When heated to 250° C. with red See also:phosphorus and hydriodic acid it gives a hydride C,4 H24. It is nitrated by nitric acid and sulphonated by sulphuric acid. With picric acid it forms a sparingly soluble picrate, which melts at 145° C. On the See also:condition of phenanthrene in alcoholic See also:solution see R. Behrend, Zeit. phys. Chem., 1892, 9, p. 405; 10, p. 265. Chromic acid oxidizes phenanthrene, first to phenanthre..;:-4uinone, and then to diphenic acid, HO2C•See also:C6H4•C6H4•See also:CO2H. Phenanthrene-quinone, [C6H412[CO]2, crystallizes in See also:orange needles which melt at 1980 C. It possesses the characteristic properties of a diketone, forming crystalline derivatives with sodium bisulphite and a dioxime with See also:hydroxylamine. It is non-volatile in See also:steam, and is odourless. Sulphurous acid reduces it to the corresponding dihydroxy See also:compound. It combines with ortho-diamines, in the presence of acetic acid, to See also:form phenazines. On the constitution of phenanthrene see See also:CHEMISTRY: § Organic. Additional information and CommentsThere are no comments yet for this article.
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