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LINSEED , the See also:seed of the See also:common See also:flax (q.v.) or See also:lint, Linum usitatissimum. These seeds, the linseed of See also:commerce, are of a lustrous See also: There are now no medicinal uses of this substance. Linseed cake, the See also:mare See also:left after the expression of the oil, is a most valuable feeding substance for See also:cattle. Linseed is subject to extensive and detrimental adulterations, resulting not only from careless harvesting and cleaning, whereby seeds of the flax See also:dodder, and other weeds and See also:grasses are mixed with it, but also from the See also:direct admixture of cheaper and inferior oil-seeds, such as See also:wild rave, See also:mustard, See also:sesame, See also:poppy, &c., the latter adulterations being known in See also:trade under the generic its value. Linseed oil, the most valuable'drying oil, is obtained by expression from the seeds, with or without the aid of See also:heat. Preliminary to the operation of pressing, the seeds are crushed and ground to a See also:fine See also:meal. See also:Cold pressing of the seeds yields a See also:golden-yellow oil, which is often used as an edible oil. Larger quantities are obtained by See also:heating the crushed seeds to 16o° F. (71 C.), and then expressing the oil. So obtained, it is somewhat turbid and yellowish-brown in colour. On storing, moisture and mucilaginous matter gradually See also:settle out. After storing several years it is known commercially as " tanked oil," and has a high value in See also:varnish-making. The delay attendant on this method of See also:purification is avoided by treating the crude oil with i to 2 % of a somewhat strong sulphuric See also:acid, which chars and carries down the bulk of the impurities. For the preparation of " artist's oil," the finest form of linseed oil, the refined oil is placed in shallow trays covered with See also:glass, and exposed to the See also:action of the See also:sun's rays. Numerous other methods of purification, some based on the oxidizing action of See also:ozone, have been suggested. The yield of oil from different classes of seed varies, but from 23 to 28 % of the See also:weight of the seed operated on should be obtained. A See also:good See also:average quality of seed weighing about 392 lb per See also:quarter has been found in practice to give out 109 lb of oil. Commercial linseed oil has a See also:peculiar, rather disagreeable See also:sharp See also:taste and See also:smell; its specific gravity is given as varying from 0.928 to 0.953, and it solidifies at about -27°. By saponification it yields a number of fatty acids—palmitic, myristic, oleic, linolic, linolenic and isolinolenic. Exposed to the See also:air in thin films, linseed oil absorbs See also:oxygen and forms " linoxyn," a resinods semi-elastic, caoutchouclike See also:mass, of uncertain See also:composition. The oil, when boiled with small proportions of litharge and minium, undergoes the See also:process of resinification in the air with greatly increased rapidity. Its most important use is in the preparation of oil paints and varnishes. By painters both raw and boiled oil are used, the latter forming the principal See also:medium in oil See also:painting, and also serving separately as the basis of all oil varnishes. Boiled oil.is prepared in a variety of ways—that most common being by heating the raw oil in an See also:iron or See also:copper See also:boiler, which, to allow for frothing, must only be about three-fourths filled. The boiler is heated by a See also:furnace, and the oil is brought gradually to the point of ebullition, at which it is maintained for two See also:hours, during which time moisture is driven off, and the scum and froth which accumulate on the See also:surface are ladled out. Then by slow degrees a proportion of " dryers " is added—usually equal weights of litharge and minium being used to the extent of 3% of the See also:charge of oil; and with these a small proportion of See also:umber is generally thrown in. After the addition of the dryers the boiling is continued two or three hours; the See also:fire is then suddenly withdrawn, and the oil is left covered up in the boiler for ten hours or more. Before sending out, it is usually stored in settling tanks for a few See also:weeks, during which time the uncombined dryers settle at the bottom as " foots." Besides the dryers already mentioned, See also:lead acetate, See also:manganese borate, manganese dioxide, See also:zinc sulphate and other bodies are used. Linseed oil is also the principal ingredient in See also:printing and litho-graphic inks. The oil for See also:ink-making is prepared by heating it in an iron pot up to the point where it either takes fire spontaneously or can be ignited with any flaming substance. After the oil has been allowed to See also:burn for some time according to the consistence of the varnish desired, the pot is covered over, and the product when cooled forms a viscid tenacious substance which in its most concentrated form may be See also:drawn into threads. By boiling this varnish with dilute nitric acid vapours of acrolein are given off, and the substance gradually becomes a solid non-adhesive mass the same as the ultimate oxidation product of both raw and boiled oil. Linseed oil is subject to various falsifications, chiefly through the addition of See also:cotton-seed, See also:niger-seed and See also:hemp-seed See also:oils; and See also:rosin oil and See also:mineral oils also are not infrequently added. Except by smell, by See also:change of specific gravity, and by deterioration of drying properties, these adulterations are difficult to detect. Additional information and CommentsThere are no comments yet for this article.
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