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KEKULE, FRIEDRICH AUGUST (1829-1896)

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Originally appearing in Volume V15, Page 718 of the 1911 Encyclopedia Britannica.
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KEKULE, See also:FRIEDRICH See also:AUGUST (1829-1896) , See also:German chemist, was See also:born at See also:Darmstadt on the 7th of See also:September 1829. While studying See also:architecture at See also:Giessen he came under the See also:influence of See also:Liebig and was induced to take up See also:chemistry. From Giessen he went to See also:Paris, and then, after a See also:short sojourn in See also:Switzerland, he visited See also:England. Both in Paris and in England he enjoyed See also:personal intercourse with the leading chemists of the See also:period. On his return to See also:Germany he started a small chemical laboratory at See also:Heidelberg, where, with a very slender equipment, he carried out several important researches. In 1858 he was appointed See also:professor of chemistry at See also:Ghent, and in 1865 was called to See also:Bonn to fill a similar position, which he held till his See also:death in that See also:town on the 13th of See also:June 1896. Kekule's See also:main importance lies in the far-reaching contributions which he made to chemical theory, especially in regard to the constitution of the See also:carbon compounds. The See also:doctrine of atomicity had already been enunciated by E. See also:Frankland, when in 1858 Kekule published a See also:paper in which, after giving reasons for regarding carbon as a tetravalent See also:element, he set forth the essential features of his famous doctrine of the linking of atoms. He explained that in substances containing several carbon atoms it must be assumed that some of the See also:affinities of each carbon See also:atom are See also:bound by the affinities of the atoms of other elements contained in the substance, and some by an equal number of the affinities of the other carbon atoms. The simplest See also:case is when two carbon atoms are combined so that one See also:affinity of the one is tied to one affinity of the other; two, therefore, of the affinities of the two atoms are occupied in keeping the two atoms together, and only the remaining six are available for atoms of other elements. The next simplest case consists in the mutual interchange of two affinity See also:units, and so on.

This conception led Kekule to his " closed-See also:

chain " or " See also:ring " theory of the constitution of See also:benzene which has been called the " most brilliant piece of prediction to be found in the whole range of organic chemistry," and this in turn led in particular to the elucidation of the constitution of the " aromatic compounds," and in See also:general to new methods of chemical See also:synthesis and decomposition, and to a deeper insight into the See also:composition of numberless organic bodies and their mutual relations. Professor F. R. Japp, in the Kekule memorial lecture he delivered before the See also:London Chemical Society on the 15th of See also:December 1897, declared that t hree-fourths of See also:modern organic chemistry is directly or indirectly the product of Kekule's benzene theory, and that without its guidance and See also:inspiration the See also:industries of the See also:coal-See also:tar See also:colours and artificial therapeutic agents in their See also:present See also:form and See also:extension would have been inconceivable. Many of Keku16's papers appeared in the Annalen der Chemie, of which he was editor, and he also published an important See also:work, Lehrbuch der organischen Chemie, of which the first three volumes are dated 1861, 1866 and 1882, while of the See also:fourth only one small See also:section was issued in 1887.

End of Article: KEKULE, FRIEDRICH AUGUST (1829-1896)

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