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STARCH

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Originally appearing in Volume V25, Page 795 of the 1911 Encyclopedia Britannica.
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STARCH , an organized product of the See also:

vegetable See also:kingdom, forming one of the most important and characteristic elements of plant See also:life. It originates within the living vegetable See also:cell through the formative activity of See also:chlorophyll under the See also:influence of See also:light, and is consequently an unfailing characteristic of all See also:plants containing that See also:body. Starch found within leaves and other See also:green parts of plants is assimilated and transformedwith See also:great rapidity; accumulations of it are carried as starch-formers, and redeposited as starch in See also:special reservoirs or portions of plants as the See also:period of maturity approaches. In this way the body is found to See also:gorge the stems of certain palms—the See also:sago, &c.—just before these plants begin to See also:form their See also:fruit; it is the See also:principal constituent of the underground See also:organs of biennial and perennial plants, tap-roots, See also:root-See also:stocks, corms, bulbs and tubers; and it is abundantly stored in many fruits and seeds, as in the cereals and pulses, in bananas, See also:bread-fruit, &c. It occurs in See also:minute granules varying in See also:diameter from •002 to •185 milli-metres; and the granules from different See also:sources have each a distinct microscopic See also:character. Under the See also:microscope these granules are seen to consist of a See also:nucleus or hilum surrounded by layers arranged concentrically or excentrically, and the relations of hilum and layers are the most distinctive features of individual starches (see H. See also:Galt, Microscopy of the Starches, 1900). Starch consists of a See also:white or yellowish-white glistening See also:powder. It is only slightly acted on by See also:cold See also:water, but under the influence of See also:heat in water it swells up, forming according to the proportions of starch and water a clouded opalescent See also:paste. The soluble portion is called granulose, and the insoluble starch-See also:cellulose; from the aqueous See also:solution See also:alcohol precipitates soluble starch. See also:Iodine acts on it in water, producing a brilliant See also:blue coloration, this reaction forming a very delicate and characteristic test. The See also:colour disappears on See also:heating, but is recovered when the mixture is cold.

Diastase and dilute boiling sulphuric See also:

acid convert starch into a form soluble in hot water, whence it passes into a See also:series of easily soluble dextrins, and finally into the See also:condition of the sugars, dextrose and maltase. Chemically, starch is a See also:carbohydrate with the See also:formula (See also:C6H,0O5),,, where n is four or more. As an economic product starch in its See also:separate condition is a most important alimentary substance, the See also:chief pure See also:food starches being See also:arrowroot, sago, See also:tapioca and cornflour. In its combined condition, in cereals, &c., starch is a useful nutritive See also:element. In its other See also:industrial relations starch is used: (1) directly, as a thickening material in See also:calico See also:printing, for the dressing and See also:finishing of many textiles, for See also:laundry purposes, adhesive paste, and powder; and (2) indirectly, for the preparation of dextrin and See also:British See also:gum and starch See also:sugar. See also:Indian See also:corn, See also:wheat and See also:rice starch are principally employed for the See also:direct applications; and for the dextrin and starch-sugar manufacture See also:potato starch is almost exclusively selected. In the preparation of starch the See also:object of the manufacturer is to burst the vegetable cell walls, to liberate the starch granules, and to See also:free them from the other cell contents with which they are associated. When, as in the See also:case of the potato, the associated cell contents, &c., are readily separated by solution and levigation the manufacture is exceedingly See also:simple. Potato starch is prepared principally by carefully washing the potatoes and in a See also:kind of rasping See also:machine reducing them to a See also:fine pulp, which is deposited in water as raw starch. The impurities of this starch—cellulose, albuminoids, fragments of potato, &c.—are separated by washing it in fine See also:sieves, through the meshes of which the pure starch alone passes. The sieves are. variously formed, some revolving, others moving horizontally or in such manner as to keep the material in agitation. The starch is then received in tanks, in which it settles, and so separates from the soluble albuminoids and salts of the potatoes.

(The See also:

waste pulp which passes over the See also:sieve is pressed, dried quickly, and sold as a See also:low-grade See also:cattle food.) The settling of the starch is much retarded by the dissolved albuminoids, and to hasten the separation small quantities of See also:alum or sulphuric acid are employed. Alum coagulates the albumen and to that extent contaminates the starch, while the acid acts on the starch itself and is difficult of neutralization. After the starch has settled, the See also:brown-coloured supernatant liquor is See also:drawn off and the starch again washed either in tanks or in a centrifugal machine. Finally it is dried by spreading it in layers over porous bricks (a See also:process not required in the case of starch washed in a centrifugal machine) and by exposure to the See also:air, after which it still retains a large proportion of water, but is in a condition for making dextrin or starch-sugar. For further drying it is ground to a rough powder, and dried thoroughly in a hot chamber, then reduced to a powder and sifted. Potato starch is also made by a " rotting " process, in which potatoes are reduced to a pulp by slicing and are then heaped up till See also:fermentation takes See also:place; See also:ion lb of potatoes yield 15–16 lb of dry starch. In dealing with the starches of the cereals, there is greater difficulty, owing to the presence of See also:gluten, which with water forms a tough elastic body difficult of solution and removal. The difficulty is experienced in greatest measure in dealing with wheat, which contains a large proportion of gluten. Wheat starch is separated in two different ways: (1) the fermentation method, which is the See also:original process, and (2) by See also:mechanical means without preliminary fermentation. In the fermentation process whole wheat or wheaten See also:meal is softened and swollen by soaking in water. Wheat grains are, in this condition, ground, and the pulp, mixed to a thickish fluid with water, is placed in tanks, where it ferments, developing acids which dissolve the gummy constituents of the wheat, with See also:part of the gluten, and render the whole less tenacious. After full fermentation, the period of which varies with the See also:weather and the process employed, the starch is separated in a washing See also:drum.

It is subsequently washed with water, which dissolves out the gluten, the starch settling in two layers—one comparatively pure, the other mixed with gluten and some branny particles. These layers are separated, the second undergoing further washing to remove the gluten, &c., and the remaining operations are analogous to those employed in the preparation of potato-starch. By the mechanical process wheaten See also:

flour is kneaded into a stiff paste, which, after resting for an See also:hour or two, is washed over a fine sieve so See also:long as the water passing off continues milky, whereby the starch is liberated and the greater part of the gluten retained as a gluey elastic See also:mass in the sieve. The starch is subsequently purified by fermentation, washing and treatment in centrifugal See also:machines. The gluten thus preserved is a useful food for diabetic patients, and is made with flour into artificial See also:macaroni and pastes, besides being valuable for other industrial purposes. The fermentation process gives about 59 lb of starch and 11 of See also:bran from 10o lb of wheat, whilst the mechanical process gives about 55 lb of starch and 12 of gluten. See also:Maize (Indian corn) starch is obtained by analogous processes, but, the proportion of gluten in the See also:grain being smaller and less tenacious in its nature, the operations, whether chemical or mechanical, See also:present fewer difficulties. Under one method the separation of maize starch is facilitated by steeping, swelling and softening the grain in a weak solution of See also:caustic soda, and favourable results are also obtained by a process in which the pulp from the crushing See also:mill is treated with water acidulated with sulphurous acid. In the preparation of rice-starch a weak solution of caustic soda is also employed for softening and swelling the grain. It is then washed with pure water, dried, ground and sifted, and again treated with alkaline water, by which the whole of the nitrogenous constituents are taken up in soluble form. ,An acid process for obtaining rice-starch is also employed, under which the grain, swollen and ground, is treated repeatedly with a solution of hydrochloric acid, which also dissolves away the non-starchy constituents of the grain. The yield is about 85 lb per See also:loo of rice.

Laundry starches are principally made from rice and from See also:

pulse. See O. Saare, See also:Die Fabrikation der Kartoffelstarke (1897).

End of Article: STARCH

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